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Button cell battery
Monday, 04 December 2006

Button cell batteries are small, thin energy cells that are commonly used in watches, hearing aids, and other electronic devices requiring a thin profile. Because of their compact nature, button type batteries are very widely used as a source of electric power for the integrated circuits of electronic apparatus. The button cell battery has become a primary power source for many portable electronic devices such as radios, hearing aids, watches, calculators and the like. These small energy cells are generally of a circular configuration and known as "button" cells because of their shape. These cells generally have diameters ranging from less than 5.8 millimeters to about 25 millimeters, and heights ranging from less than 2.0 millimeters up to about 15 millimeters. Button-type batteries, because of their compact size, permit electronic devices to be built which themselves are very small or compact. In order to maintain the overall electronic devices as compact as possible, the electronic devices are usually designed with cavities to accommodate miniature batteries as their power source. The cavities are usually made so that a battery can be snugly positioned therein, thus making electronic contact with appropriate terminals within the device. In electronic watches, button cells are arranged horizontally, either in a recess arranged in the printed circuit arranged within the case, or in a recess provided in the back cover of the case sealed by a cover to make replacement of the battery easier when it is worn out. The connections of the battery terminals to the electronic circuit are achieved by means of metal clamps, permanently fixed to the printed circuit or to the frame. To accommodate the electronic component manufacturers, the battery industry has adopted several conventional size button cells which the manufacturer can rely upon in designing their devices which require portable power sources. Generally, button cells are divided into four groups, i.e., silver oxide cells, mercury cells, lithium cells and alkali-manganese cells. A silver oxide cell's content is silver oxide and silver metal, and the shell is made of zinc, iron and nickel. Button cells of this construction may contain different electrochemical systems. Button cells with rechargeable Ni/Cd systems are very widespread. Button cells with metal oxide/metal hydride systems, in particular Ni/Nickel hydride cells, have been acquiring increasing importance. In addition to these secondary systems, which also include secondary lithium systems, primary lithium systems and other high-energy systems such as silver oxide/zinc systems, are available in button-cell form.

Metal air cells are electrochemical cells where the oxygen in the air is the cathode material and a metal material is the anode material. Electrochemical cells of the button type are incorporated in many devices for producing electrical power. Button cells employing nonaqueous electrolytes and highly active metal anodes are particularly advantageous for certain uses while cells employing aqueous electrolytes are preferred for other uses. Metal air cells convert atmospheric oxygen to hydroxide in the air cathode, the hydroxide then migrating to the anode, where it causes the metal contained therein to oxidize. In many instances the preferred anode material is zinc. Zinc/air depolarized cells are typically in the form of miniature button cells which have particular utility as batteries for electronic hearing aids including programmable type hearing aids. Such miniature cells typically have a disk-like cylindrical shape of diameter between about 4 and 12 mm and a height between about 2 and 6 mm. Zinc air cells can also be produced in somewhat larger sizes having a cylindrical casing of size comparable to conventional AAAA, AAA, AA, C and D size alkaline cells. The miniature zinc/air button cell typically comprises an anode casing (anode cup), and a cathode casing (cathode cup). The anode casing and cathode casing typically each have a closed end and an open end. An electrical insulating material can be placed around the outside surface of the anode casing. After the necessary materials are inserted into the anode and cathode casings, the open end of the anode casing is typically inserted into the open end of the cathode casing and the cell sealed by crimping. Zinc/air button cells are generally constructed with an apertured cup which contains a hydrophobic layer of a material such as polytetrafluoroethylene (PTFE) adjacent the apertures to prevent electrolyte leakage but which permits air inflow. The apertures in the cup permit the influx of the cathode depolarizing air. The cup or container also contains the catalytic cathode and thereby comprises the positive terminal for the cell. To prevent gas from accumulating in the cell during cyclic charge/discharge operations, the negative electrode is usually designed to have a larger capacity than the positive electrode. Zinc/air cells are unique as compared to other button cells in that a void must be provided in the anode portion of the cell. The void is used to accommodate the substantial increase in volume during discharge which occurs, for example, when zinc oxide is produced as the discharge product of zinc anode. The need for this void comes from the sensitivity of the air cathode to pressure. Typical button-type alkaline electrochemical cells have a negative electrode (anode) with zinc or a zinc alloy as the active material and an alkaline electrolyte, such as potassium hydroxide. To reduce leakage, especially caused by gassing inside the cell during the electrochemical reaction, mercury has been added to the cell. Button cells on the market today employ a small amount of mercury. However, it has become apparent that mercury can be hazardous to the environment and to the health of humans and animals.

Implantable devices are becoming more and more complex and commonly include sophisticated data processing hardware such as microprocessors, memory devices, or other large scale integration (LSI) devices. A wide range of electronic devices are designed for surgical implantation into humans or animals. One common example is the cardiac pacemaker. Other examples of implantable devices include devices for stimulating or sensing portions of the brain, spinal cord, muscles, bones, nerves, glands or other body organs or tissues. Such devices are designed for transmitting signals to remote sensing devices. Implantable electrochemical cells are hermetically sealed using an insulating glass to separate the terminal pin from the case. Power sources of this type prevent internal components, such as the electrolyte, from coming into contact with body tissue or sensitive electrical components of the associated implantable medical device. An implantable electrochemical cell may include, for example, cells employing lithium as an anode material and polycarbon monofluoride as an active cathode material. Within such cells, a metal foil anode coated with lithium is provided in combination with polycarbon monofluoride formed on a current collector. A polymeric separator is positioned between the anode and the cathode thereby forming an electrode structure. The electrode structure is mounted within a cell housing which is flooded with a liquid non-aqueous electrolyte. Appropriate electrical contacts are provided to the anode and cathode.